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Electrochemical reduction of carbon dioxide to produce large-benefit ethylene is frequently limited by weak selectivity and produce of multi-carbon products. To address this, we suggest a cyanamide-coordinated isolated copper framework with both of those metallic copper (Cu0) and charged copper (Cu1+) web sites as an productive electrocatalyst to the reduction of carbon dioxide to ethylene. Our operando electrochemical characterizations and theoretical calculations expose that copper atoms inside the Cuδ+NCN complex boost carbon dioxide activation by improving upon area carbon monoxide adsorption, while delocalized electrons close to copper web sites facilitate carbon-carbon coupling by lessening the Gibbs free of charge energy for *CHC formation.
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An herbicide that gives extensive-lasting foliar and residual control of a broad-spectrum of woody vines, troublesome brush and broadleaf weeds.
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Furthermore, the spacious crystal structure resulted from parallel aligned [NCN]two− would greatest exposure from the active websites and delivers about plentiful channel to the adsorption of reagents.